Its not uncommon in brass tubes in cooling water service that is contaminated with. Principles and practices of mechanical integrity for. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the. Stress corrosion cracking proceeds more rapidly at high temperatures. Covers ammonia characteristics and hazards, inspection and maintenance of equipment, startup issues, reference standards, safety equipment, and log book recordkeeping. Stress corrosion cracking of ammonia storage spheres survery and panel discussion. This type of failure is known as stress corrosion cracking, often abbreviated to scc.
Stress corrosion cracking in the ammonia refrigeration industry. Systems with airoxygen contamination also tend to be particularly vulnerable to this issue. Water in ammonia to protect against stress corrosion. The stress can originate from an externally applied force, thermal. Stresscorrosion cracking of steel in liquefied ammonia is traced from its early recognition in the 1950s, from experiences in agricultural and industrial use from nace national association of corrosion engineers recommended dot department of transportation regulations to prevent damage, and from laboratory studies to explain the factors involved. Learn the latest recommended practices to manage the mechanical integrity of industrial ammonia refrigeration systems. Stress corrosion cracking of linepipe steels in anhydrous.
Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Stress corrosion cracking in a brewery paul mueller company. On discovery of a source of moist ammonia in the system, associated with the location of failure, intergranular stresscorrosion cracking scc was identified as the failure mechanism. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Industrial refrigeration consortium, 15 university avenue suite 3184, madison, wi 537061607. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in contaminated cooling water service. The cold front industrial refrigeration consortium. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking of steel in liquefied ammonia service a. Stresscorrosion cracking in copper refrigerant tubing. Ammonia corrosion can cause stress corrosion cracking in steels.
Prevention phas for ammonia refrigeration systems thank you. Ammonia or nitrides ammonia and nitrogen combinations, in the presence of moisture, cause this type of corrosion. American national standard for ansiiiar 22008, includes. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Ineffective refrigeration due to excess oil within the system, causing the system to work harder than necessary, thus stressing the system components.
Electrochemistry of stress corrosion cracking of brass m. New cases of stress corrosion cracking in large atmospheric ammonia storage tanks. They also indicate that if vessels operated above 23degrees fahrenheit are postweld heat treated, concerns about stresscorrosion cracking are greatly reduced. A modified design, incorporating annealing of the formed copper tube section, was recommended to. The main publications which have legally binding responsibilities for the owners of the systems are. Stress corrosion cracking in refrigeration systems request pdf. Guidelines for startup, inspection, and maintenance of ammonia mechanical refrigerating systems. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the. Often, pitting corrosion is associated with the stress corrosion cracking phenomena. Ammonia refrigeration can be potentially dangerous and lethal if an ammonia leak occurs in the.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Stress corrosion cracking ammonia psm rmp training. The electrochemistry and mechanism of stress corrosion. We have put a vent on the vapor space of the sphere to vent any oxygen. Defining and diagnosing, provided an overview of stresscorrosion cracking scc and its relation to equipment used in industrial ammonia refrigeration systems. If moisture is present in an alkaline environment it may absorb ammonia and such solutions, in conjunction with residual stress, can initiate stress corrosion cracking. In the refrigerant cycle of an ammonia system, aluminium constructed components. Stress corrosion stress corrosion cracking refers to the combined influence of tensile stress applied or internal and corrosive environment. Conversion otec system is more complex in that in at least one design, the shellandtube. The material can crack without any significant deformation or obvious deterioration of the material. New hvac is real, yasushi kelly sasaki of mayekawa declared during the hvac parallel session at atmo america 2017, in a sign that natural refrigerants and ammonia in particular are increasingly ready to move beyond refrigeration into heating, ventilation and airconditioning applications.
However, other contaminants such as sulphur dioxide can cause cracking. Ammonia refrigeration systems are great economical refrigeration systems for largescale cooling, however, there are some side effects from using ammonia in refrigeration systems such as the ones described above in food cold storage applications. You will be able to immediately apply what you learn in this course to ensure the ongoing reliability and safety of industrial. Stresscorrosion cracking of steels in ammonia with. Four factors, are required before stress corrosion cracking can occur. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the cracking mechanism on brass which occurs in an aqueous solution, the cracking of steel equipment occurs in anhydrous ammonia.
The cupric ion present in the solution appears as an oxidant that provides a cathodic reaction and induces stress corrosion cracking of brass in ammonia and ammoniacal solutions. Mechanisms of stresscorrosion cracking asm international. Materials performance and evaluation, asm international, pp. Corrosionpedia what is stress corrosion cracking scc.
There are specific stresscracking agents for brasses, these are usually ammonia or its derivatives. This type of failure is referred to as stress corrosion cracking scc. A modified design, incorporating annealing of the formed copper tube section, was recommended to avoid future failures. Electrochemistry of stress corrosion cracking of brass. Ammonia mechanical refrigerating systems american national standard for ansiiiar 22008. Ammonia spills and the effect of ammonia on products stored in refrigerated warehouses. See iiar 22008, appendix j, iiar 22014, appendix h, and iiar bulletin 110, appendix e, which suggest that ensuring a minimum water content can help prevent stresscorrosion cracking.
Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Failure analysis of stresscorrosion cracking, chapter 18, stresscorrosion cracking. There are three factors under which stress corrosion cracking is possible a corrosive mediumenvironment b material and c tensile stress. Legislation relating to ammonia refrigeration systems there are various uk and eu laws and regulations which apply to plants with ammonia refrigeration systems. Two refrigeration system ammonia storage vessels of this steel also showed scc in cold formed vessel heads near welds that were not postweld heat treated. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. The course will emphasize refrigerant piping and pressure vessels but mechanical integrity practices for other components will be presented as well. Stress corrosion cracking of steel in liquefied ammonia. The different hygroscopicity of these oils leads to different corrosion conditions. The stress can originate from an externally applied force, thermal stress, or residual stress from welding. How to make sure your ammonia refrigeration systems are safe. In that article, we identified a number of conditions that tend to promote or enable stresscorrosion cracking. Stress corrosion cracking in refrigeration systems.
A corrosion inhibitor for ammoniawater absorption circuits for heat pumps and refrigerators in which the operating fluid is an ammoniawater solution, the inhibitor being added to said solution and comprising zinc borate in mixture with a buffer formed from potassium hydroxides and nitrates. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of. Stress corrosion cracking scc is a generic term describing the initiation and propagation of cracks that can occur in metals when subjected to stress in the presence of an enabling chemical environment. Pugh, the theory of stress corrosion cracking in alloys j.
Examples of catastrophic failure of nh3 refrigeration vessels caused. Institute of refrigeration safety code of practice for. This may result in ammonia weeping from a crack within the refrigeration system. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. Ammonia stress corrosion cracking scc has been around a long time.
Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. To combat this, we recommend insulation materials such as armaflex, which has a mass share of ammonia that. The international institute of ammonia refrigeration makes no warranty or representation and assumes no. In refrigeration systems that rely solely on high pressure trips for. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Stress corrosion cracking scc is a phenomenon that occurs occasionally. Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. This code of practice is intended to apply within the united kingdom to systems where the motors driving the compressors have a total installed power of more than 25kw, including any standby.
Contact information 2020 board of regents of the university of wisconsin system. While it is rare, formed parts can develop fractures after they are placed in service. The stress corrosion cracking scc behavior of electricresistancewelded erw api grades x42, x46, x52, and x60 linepipe in liquid ammonia has been evaluated for the base metal, erw weldments, and girth weldments. Also tanks for transporting liquid ammonia, like rail tank cars.
Stress corrosion cracking in ammonia storage iffco. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. Stress corrosion cracking international institute of. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Refrigeration oils used in ammonia systems are either mineral and synthetic oils insoluble in ammonia or polyalkylene glycol pag synthetic oils, which are soluble in ammonia and have been available since approx. New informative appendix j stress corrosion cracking. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. Cases of stress corrosion cracking scc in steel vessels using nh3 have.
1034 225 444 1436 49 1525 899 305 636 862 237 192 10 399 111 278 923 633 445 250 1331 792 1373 399 320 1256 1188 1295 412 1484 997 150 632 238 99 1143 244 189 1009 1019 1036 549 31 1375 316 13 787